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Creators/Authors contains: "Sivaguru, Jayaraman"

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  1. ; ; (, The Journal of Physical Chemistry A)
    Free, publicly-accessible full text available May 1, 2026
  2. ; ; (, Molecules)
    Maleimides serve as crucial components in various synthetic processes and are of significant interest to researchers in bioorganic chemistry and biotechnology. Although thermal reactions involving maleimides have been studied extensively, light-mediated reactions with maleimides remain relatively underutilized. This review focuses on understanding the behavior of maleimides in their excited state, particularly their role as synthetic scaffolds for excited-state reactions. Specific emphasis is placed on the diverse photoreactions involving maleimides and photophysical evaluation from our research group. 
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  3. ; ; ; ; ; (, ACS Catalysis)
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  4. ; ; ; ; (, Journal of the American Chemical Society)
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  5. ; ; ; ; ; (, Journal of Photochemistry and Photobiology A: Chemistry)
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  6. ; ; ; (, Nature Chemistry)
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  7. ; ; (, Journal of Photochemistry and Photobiology)
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  8. ; ; ; ; (, Photochemistry and Photobiology)
    Abstract The irradiation of β‐enaminones, generated in situ from cyclic 1,3‐diketones and activated alkenes leads to polyheterocyclic skeletons. The photoproduct chemoselectivity depends on the type of cyclic 1,3‐diketones employed viz., 2‐acetylcyclopentanone and 2‐acetylcyclohexanone. The observed chemoselectivity was rationalized based on the Dieckmann‐Kon rule. 
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  9. ; ; ; ; ; ; ; ; (, Photochemistry and Photobiology)
    The study evaluates compatibility of stabilizers with dye doped liquid crystal (LC) scaffolds that are used in electronically dimmable materials. The photodegradation of the materials was investigated and suitable stabilizers were evaluated to slow the degradation process. Various types of benzotriazole-based stabilizers were evaluated for stabilizing the liquid crystals. Based on spin trapping experiments, radicals generated upon UV exposure is likely responsible for the degradation of the system. The radical generation is competitively inhibited by the addition of stabilizers. 
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  10. ; ; (, Photochemical & Photobiological Sciences)
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